TIH · Toxic inhalation hazard · Zone B · Isolate immediately upwind before approach

ERG 2024 · Guide 142

Oxidizers - Toxic (Liquid)

UN3388 · Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B)

Also listed as: Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B)

Class 5.1TIH · Zone B

CHEMTREC · 24/7

1-800-424-9300

Right now: Move upwind. Isolate 100 m minimum. Deny entry. Call CHEMTREC with shipping paper in hand.

More contacts →

Green Table 1 — Initial isolation & protective action distances

Full table →

Small spill · Isolate

30 m

Day

0.1 km

Night

0.1 km

Large spill · Isolate

150 m

Day

0.3 km

Night

0.5 km

Potential Hazards

Health

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.
Fire may produce irritating, corrosive and/or toxic gases.
Toxic/flammable fumes may accumulate in confined areas (basement, tanks, tank cars, etc.).
Runoff from fire control or dilution water may cause environmental contamination.

Fire or explosion

These substances will accelerate burning when involved in a fire.
May explode from heat or contamination.
Some will react explosively with hydrocarbons (fuels).
May ignite combustibles (wood, paper, oil, clothing, etc.).
Containers may explode when heated.
Runoff may create fire or explosion hazard.

Public Safety

General

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
Keep unauthorized personnel away.
Stay upwind, uphill and/or upstream.
Ventilate closed spaces before entering, but only if properly trained and equipped.

Protective clothing

Wear positive pressure self-contained breathing apparatus (SCBA).
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

Evacuation

Immediate precautionary measure
Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
Spill
For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.
Fire
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Emergency Response

Fire

Small Fire

Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.

Large Fire

Flood fire area with water from a distance.
Do not move cargo or vehicle if cargo has been exposed to heat.
If it can be done safely, move undamaged containers away from the area around the fire.

Fire Involving Tanks, Rail Tank Cars or Highway Tanks

Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
Cool containers with flooding quantities of water until well after fire is out.
ALWAYS stay away from tanks in direct contact with flames.
For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Spill or leak

Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Stop leak if you can do it without risk.
Use water spray to reduce vapors or divert vapor cloud drift.
Do not get water inside containers.
Small Liquid Spill
Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.

Large Spill

Dike far ahead of liquid spill for later disposal.

First Aid

Refer to the “General First Aid” section.

Specific First Aid:

Contaminated clothing may be a fire risk when dry.

TIH · Toxic inhalation hazard · Zone B · Isolate immediately upwind before approach

ERG 2024 · Guide 142

Oxidizers - Toxic (Liquid)

UN3388 · Poisonous by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B)

Also listed as: Toxic by inhalation liquid, oxidizing, n.o.s. (Inhalation Hazard Zone B)

Class 5.1TIH · Zone B

CHEMTREC · 24/7

1-800-424-9300

Right now: Move upwind. Isolate 100 m minimum. Deny entry. Call CHEMTREC with shipping paper in hand.

More contacts →

Green Table 1 — Initial isolation & protective action distances

Full table →

Small spill · Isolate

30 m

Day

0.1 km

Night

0.1 km

Large spill · Isolate

150 m

Day

0.3 km

Night

0.5 km

Potential Hazards

Health

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death.
Fire may produce irritating, corrosive and/or toxic gases.
Toxic/flammable fumes may accumulate in confined areas (basement, tanks, tank cars, etc.).
Runoff from fire control or dilution water may cause environmental contamination.

Fire or explosion

These substances will accelerate burning when involved in a fire.
May explode from heat or contamination.
Some will react explosively with hydrocarbons (fuels).
May ignite combustibles (wood, paper, oil, clothing, etc.).
Containers may explode when heated.
Runoff may create fire or explosion hazard.

Public Safety

General

CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
Keep unauthorized personnel away.
Stay upwind, uphill and/or upstream.
Ventilate closed spaces before entering, but only if properly trained and equipped.

Protective clothing

Wear positive pressure self-contained breathing apparatus (SCBA).
Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.

Evacuation

Immediate precautionary measure
Isolate spill or leak area for at least 50 meters (150 feet) in all directions.
Spill
For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.
Fire
If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.

Emergency Response

Fire

Small Fire

Use water. Do not use dry chemicals or foams. CO2 or Halon® may provide limited control.

Large Fire

Flood fire area with water from a distance.
Do not move cargo or vehicle if cargo has been exposed to heat.
If it can be done safely, move undamaged containers away from the area around the fire.

Fire Involving Tanks, Rail Tank Cars or Highway Tanks

Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
Cool containers with flooding quantities of water until well after fire is out.
ALWAYS stay away from tanks in direct contact with flames.
For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

Spill or leak

Keep combustibles (wood, paper, oil, etc.) away from spilled material.
Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
Stop leak if you can do it without risk.
Use water spray to reduce vapors or divert vapor cloud drift.
Do not get water inside containers.
Small Liquid Spill
Use a non-combustible material like vermiculite or sand to soak up the product and place into a container for later disposal.

Large Spill

Dike far ahead of liquid spill for later disposal.

First Aid

Refer to the “General First Aid” section.

Specific First Aid:

Contaminated clothing may be a fire risk when dry.