Flammable Liquids - Toxic

• CAUTION: The majority of these products have a very low flash point. Use of water spray when fighting fire may be inefficient.
• CAUTION: Methanol (UN1230) will burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.)

Small Fire

• Dry chemical, CO2, water spray or alcohol-resistant foam.

Large Fire

• Water spray, fog or alcohol-resistant foam.
• If it can be done safely, move undamaged containers away from the area around the fire.
• Dike runoff from fire control for later disposal.
• Avoid aiming straight or solid streams directly onto the product.

Fire Involving Tanks, Rail Tank Cars or Highway Tanks

• Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
• Cool containers with flooding quantities of water until well after fire is out.
• Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
• ALWAYS stay away from tanks in direct contact with flames.
• For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.

• ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
• All equipment used when handling the product must be grounded.
• Do not touch or walk through spilled material.
• Stop leak if you can do it without risk.
• Prevent entry into waterways, sewers, basements or confined areas.
• A vapor-suppressing foam may be used to reduce vapors.

Small Spill

• Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal.
• Use clean, non-sparking tools to collect absorbed material.

Large Spill

• Dike far ahead of liquid spill for later disposal.
• Water spray may reduce vapor, but may not prevent ignition in closed spaces.